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I have no idea about the raw stones, but for your alternative, have you looked at star sapphires? They come in almost every color. It is my favorite stone and IMO it is one of the most beautiful.
@tksjewelry: No, I don't think I have. Do you have any pictures of nice ones to hand? If not, I'll trawl through Google later.
@tksjewelry: Oh, those look interesting. Do you have one of those or something else? I like the white one best, which figures because I'm edging away from coloured stones for engagement.
You could also consider a moonstone. Here's a picture of Anna Paquin's e-ring. Its debated if its an actual diamond or a moonstone, my bet is on the moonstone. Its beautiful either way!!!

@VickyAurea: I don't, but a medium blue one was my moms engagement ring. I will have one, DH know them by heart what I want. I was super not happy when he got my engagement ring ordered with a diamond. We had them hold my ring for a few months for lack of cash to pick it up, it was custom designed for the wedding band DH made for me. DH has been super sneaky lately and I have a feeling that he may have changed out the center stone. Of course that could just be me getting my hopes up.
The closest thing I can think of to the rough diamond look is quartz. I wouldn't recommend it for an ering, though, because of its softness. To give an example, amethyst is a type of quartz, and is strong enough to be used in jewelry, but wouldn't hold up to everyday wear on a ring to the same extent that a raw diamond would. What you could do is go with raw quartz when on a budget and then upgrade to raw diamond later down the road. Or keep upgrading quartz every few years. Moonstone wouldn't hold up well down the road, either.
Oh, just saw you don't like the idea of quartz. What about colorless quartz? Perhaps a raw sapphire? Star sapphires are pretty cool and come in different colors, may not have the "rough" diamond look you like, but would be neat.
@aaalexx:It's a good thought, though they are too big for me, generally. Certainly one like the pic is too big - a different pic may make me feel differently but I have only seen pics like this of big stones. It's the right line of thinking, though! Out of the box is the way forward.
@abirdword: It doesn't have to be the rough look in particular, though I do like that.
I'm trying to steer clear of diamonds, it isn't a money thing (though money would be my 2nd reason if I needed one).
Quartz, yes... are there specific names for different types? I don't know a great deal about about stones, all I know is diamond, white topaz, white sapphire, cubic zirconia, star sapphire, moonstone.... What others are there that are white/off white/pale/just not brightly coloured?
I like these but a) they're diamond and b) the first one costs $45,000!


ETA: Resizing the images isn't working: sorry they're so big.
I really like opal. :) It doesn't have a rough diamond look, but it's white and iridescent. Pearl is another option - for a long time I wanted a pearl engagement ring.
Zircon and topaz comes in clear/white as well... but they look more "finished" than rough.
I wouldn't recommend opal at all. It is really beautiful and I have several of them but opal won't take a daily use well - I had two rings with opals and both shattered within a year :( Not what I would want in an engagement ring...
If you don't want a diamond, I would recommend some stone from the corund family - ruby or sapphire - they come in all colors - even colorless if you like the clear look.
If you really want the "raw look" quartz in the clear variety (rock crystal) is actually a better chice than opal durability-wise - its hardness should be almost 7 whereas opal's is only 5.5!
For me, my number one clear rock is Moissanite (hard, cheap, beautiful), than synthetic diamond (conflict-free, harder, almost as beautiful) and white sapphire (cheaper than diamond, still reasonably hard and still pretty enough) - I want my ring to last forever so I am only mentioning what I would choose for myself ;)
I found this ring on etsy, it's a rough amethyst

http://www.etsy.com/listing/86483206/black-rough-amethyst-ring
This one's also cool, it's apetite!
http://www.etsy.com/listing/87331436/apatite-rough-stone-ring-in-sterling

You might want to look at white druzy quartz. It has the rough look that you're looking for.
I would look into a rough, regular sapphire (not the star sapphire). It has pretty hard on the Mohs scale of 9.0. And, it would last and endure abuse much better than a quartz or a moonstone. // Maybe you can order a "custom item" from the etsy sellers? Or go to the natural sapphire company online and buy a loose gem?
Oooh .. I just stumbled across some sea glass rings on Etsy. They are really unique! And recycling glass ;) Always a plus!
that one was kind of large, but I bet you could make a special request.
I would suggest going into a rock & mineral store and asking to see different types of semi-precious gemstones. I can think of several that look like your rough diamond pic, but I don't know what they are called!
be sure to ask how hard the stones are too. some will be too soft and fragile. if you want your ring to last forever, then you might want to steer away from the soft ones.
one stone I was thinking is quartz. but I'm not sure if it's strong enough for an e-ring?
like this:
or this:
I have a labradorite ring that I'm just in love with. Labradorite has a really cool inner glow like a moonstone but a rough and included look like a raw diamond.
Examples:


Wow, thanks everyone, so many suggestions! I don't have time to look into them all right now but I will soon and then I'll be back with any questions about the stones you've mentioned, as I haven't heard of most of them.
Hardness isn't something I know anything about. I suppose I do need to take that into consideration, though.
This is raw topaz, which I think has the look you're going for; and it's hardness 8, so it should hold up pretty well.

@moara: That's lovely, thank you! I couldn't find many raw topaz on etsy, though.
I'm currently looking at labradorite on etsy. They tend to be huge, as do moonstones. The UK taste in engagement rings is already much smaller stones than in the US, so add a moonstone into the equation and they look enormous to me.
For labradorites, I really like this one on etsy because it looks traditional, with 6 prongs and a gem stone, with just a little twist.
Someone suggested going to a gemstone shop - I've never seen or heard of a place that specialises in gemstones. Other than high street jewellers, I'd have no idea who to ask about stones and rings, so any tips would be most welcome. Are these shops common?
The good news is that my SO likes the labradorite I posted just above. He calls it a "labrador". Bad news is I don't think he's "ready" to buy it and he reckons we can't afford to buy a ring right now (we totally can).
Try this site, they sell lots of beautiful rough (sapphires, spinels...) with that raw but shimmery and pretty look.
http://www.faceters.com/rough/
@VickyAurea: Well I hope you can twist his arm a little, that Etsy ring you posted above is beautiful!
@BonbonBunny: I second a pearl, mostly because that's what I have :). The only thing is that I have to take it off to do pretty much ANYTHING! I know they are super delicate but we have the plan for it that if anything happens to any part of the ring they will replace it.
Vicky, at the bottom of this list is a bunch of British lapidary and rock clubs:
http://www.lapidaryworld.com/clubs_worldwide.html
They would know about rock and gem stores or sales.
I am really sorry to say this - but whether you find what you want may have to do with what part of the ring you lovedmost. Diamonds even in the rough form have a very special cleavage and luster, it's described as 'adamantine' which was a Roman word for diamonds and an adjective for being hard and durable (think being adamant about something).
OTOH, there are a LOT of gorgeous rocks and gems out there in their raw form. It might be worth going to a mineral show and seeing just what's there!
Needless Markup, I mean Neiman Marcus sells rings exactly what you are looking for but in diamond that range from $5000-$11000. They are by a designer called Diamonds in the Rough. They are gorgeous rings, I so want one of their eternity bands for my wedding ring! Good luck!
I know people sell rough moissanite crystals on eBay. I'd imagine someone could make a custom ring for you on Etsy. Moissy has the benefit of being almost as hard as diamond, too. Here's an example:
or
Just realized how old this thread was. Probably too late, but I just saw this on Etsy tonight:
http://www.etsy.com/listing/78166231/clearance-montana-sapphire-and-recycled
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Hey bees,
My SO and I have been looking at engagement rings on etsy and we really like the unusual ones, such as those with a rough diamond look. However, I'm not keen on diamonds themselves, so is there something else that looks like rough diamond but isn't made of real diamond? Preferably not a coloured quartz but willing to take on any suggestions.
Alternatively, what else is unusual and pretty for an engagement ring?
Thanks!